I'm teaching informatics on Gymnázium Metodova and here I held a PHP Course for students of 4 year high-school study. It was a kind of communicative course, where students gave me some problems they had while programming, and I've tried to solve them.
Course was closed because of small amount of students coming to it (I think, and hope, that was not because of me, but because of character of school, because it haven't got any programming classes).
No materials were created for these courses, while the main idea was real-time generation of content based on student's requests.